The Current Formation Processes in Lithium Power Sources with SiO2 – C Composite Cathode Array

Main Article Content

I.F. Myronyuk
V.M. Sachko
V.I. Mandzyuk

Abstract

The current formation process in lithium power source (LPS) with SiO2 –22% C composition cathode is explored in this work using galvanostatic cycling, cyclic voltammetry and impedance spectroscopy methods. It is set that specific capacity of LPS is 1757 mA∙h/g at its discharge in the mode C/20. Further cycling of LPS is accompanied by a sharp decline in specific capacity (irreversible capacity after the first cycle exceeds 95 %) due to formation of solid electrolyte interface of LiF composition and LiхSiO2 compound, in which lithium is not oxidized to the ion state during charging of source. It is found that the insertion of lithium ions into cathode material to the value x = 1,8 results in reduction of their diffusion coefficient on 4 orders (DLi = 2,2∙10 -14 ÷ 2,1∙10 -18 сm2/s).

Article Details

How to Cite
Myronyuk, I., Sachko, V., & Mandzyuk, V. (2015). The Current Formation Processes in Lithium Power Sources with SiO2 – C Composite Cathode: Array. Physics and Chemistry of Solid State, 16(3), 569–575. https://doi.org/10.15330/pcss.16.3.569-575
Section
Scientific articles

References

J.-M. Tarascon, M. Armand, Nature 414(6861), 359 (2001).

R. A. Sharma, R. N. Seefurth, J. Electrochem. Soc. 123(12), 1763 (1976).

B. A. Boukamp, G. C. Lesh, R. A. Huggins, J. Electrochem. Soc. 128(4), 725 (1981).

C. van der Marel, G. J. B. Vinke, W. van der Lugt, Solid State Commun. 54(11), 917 (1985).

L. Y. Beaulieua, K. W. Ebermanb, R. L. Turnerb, L. J. Krauseb, J. R. Dahn, Electrochem. Solid State Lett. 4 (9), A137 (2001).

H. Li, X. Huang, L. Chen, G. Zhou, Z. Zhang, D. Yu, Y. J. Mo, N. Pei, Solid State Ionics 135 (1-4), 181 (2000).

J. H. Ryu, J. W. Kim, Y.-E. Sung, S. M. Oh, Electrochem. Solid-State Lett. 7 (10), A306 (2004).

W.-R. Liu, Z.-Z. Guo, W.-S. Young, D.-Z. Shein, H.-C. Wu, M.-H. Yang, N.-L. Wu, J. Power Sources 140 (1), 139 (2005).

M.-H. Park, M. G. Kim, J. Choo, K. Kim, J. Kim, S. Ahn, Y. Cui, J. Cho, Nano Lett. 9 (11), 3844 (2009).

T. Song, J. Xia, J.-H. Lee, D. H. Lee, M.-S. Kwon, J.-M. Choi, J. Wu, S. K. Doo, H. Chang, W. I. Park, D. S. Zang, H. Kim, Y. Huang, K.-C. Hwang, J. A. Rogers, U. Park, Nano Lett. 10 (5), 1710 (2010).

H. Kim, J. Cho, Nano Lett. 8 (11), 3688 (2008).

L.-F. Cui, R. Ruffo, C. K. Chan, H. Peng, Y. Cui, Nano Lett. 9 (1), 491 (2009).

F. Tuinstra, J. L. Koenig, J. Chem. Phys. 53, 1126 (1970).

H. Kim, B. Han, J. Choo, J. Cho, Angew. Chem. Int. Ed. 47 (52), 10151 (2008).

V.І.Mandzjuk, V.M.Sachko, І.F.Mironjuk, Physics and Chemistry of Solid State. 15 (1), 130 (2014).

J. Yang Y. Takeda, N. Imanishi, C. Capiglia, J. Y. Xie, O. Yamamoto, Solid State Ionics 152-153, 125 (2002).

T. Tabuchi, H. Yasuda, M. Yamachi, J. Power Sources 146 (1-2), 507 (2005).

T. Zhang, J. Gao, H. P. Zhang, L. C. Yang, Y. P. Wu, H. Q. Wu, Electrochem. Commun. 9 (5), 886 (2007).

M. Miyachi, H. Yamamoto, H. Kawai, J. Electrochem. Soc. 154 (4), A376 (2007).

J.-H. Kim, H.-J. Sohn, H. Kim, G. Jeong, W. Choi, J. Power Sources. 170 (2), 456 (2007).

C. H. Doh, C. W.Park, H. M. Shin, D. H. Kim, Y. D. Chung, S. I. Moon, B. S. Jin, H. S. Kim, A. Veluchamy, J. Power Sources 179 (1), 367 (2008).

Yu. R. Ren, M. Z.Qu, Z. L. Yu, Sci. China Ser. B – Chem. 52 (12), 2047 (2009).

C. Guo, D. Wang, Q. Wang, B. Wang, T. Liu, Int. J. Electrochem. Sci. 7 (9), 8745 (2012).

І. F. Mironjuk, V. V. Lobanov, B. K. Ostafіjchuk, V. І. Mandzjuk, І. І. Grigorchak, L. S. Jablon', Physics and Chemistry of Solid State 2 (4), 653 (2001).

B.K. Ostafіjchuk, І.F. Mironjuk, V. O. Kocjubins'kij, V. І. Mandzjuk, Ju. V. Gavenchuk, Nanosistemi, nanomaterіali, nanotehnologіyi 4 (3), 585 (2006).

І.F. Mironjuk, V.M. Ogenko, B.K. Ostafіjchuk, V.І. Mandzjuk, І.І. Grigorchak, Physics and Chemistry of Solid State 2(4), 661 (2001).

V.І. Mandzjuk, І.F. Mironjuk, V.A. T'ortih, І.S. Berezovs'ka, V.V. Janishpol's'kij, Fіzika і hіmіja tverdogo tіla. 5 (2), 679 (2010).

V.І. Mandzjuk, І.F. Mironjuk, B.K. Ostafіjchuk, І.І. Grigorchak, Physics and Chemistry of Solid State 5 (4), 767 (2004).

І.F. Mironjuk, B.K. Ostafіjchuk, V.І. Mandzjuk, B.P. Bahmatjuk, І.І. Grigorchak, R.J. Rіpec'kij, Physics and Chemistry of Solid State 6(2), 212 (2005).

V.V. Bukatjuk, V.I. Mandzjuk, I.F. Mironjuk, III Vserossijskaja molodjozhnaja konferencija s jelementami nauchnoj shkoly “Funkcional'nye nanomaterialy i vysokochistye veshhestva” (IMET RAN RHTU im. D.I. Mendeleeva, Moskva, 2012), s. 95.

V. V. Gumenyak, I. F. Myronyuk, V. I. Mandzyuk, HІV mіzhnarodna konferencіja “Fіzika і tehnologіja tonkih plіvok ta nanosistem” (Vidavnictvo Prikarpats'kogo nacіonal'nogo unіversitetu іm. Vasilja Stefanika, Іvano-Frankіvs'k, 2013), s. 217.

M. Noel, V. Suryanarayanan, J. PowerSources 111, 193(2002).

C.-H. Doh, A. Veluchamy, D.-J. Lee, J.-H. Lee, B.-S. Jin, S.-I. Moon, C.-W. Park, D.-W. Kim, Bull. Korean Chem. Soc. 31 (5), 1257 (2010).

Z.B. Stojnov, B.M. Grafov, B. Savova-Stojnova, V.V. Elkin. Jelektrohimicheskij impedans (Nauka, Moskva, 1991).

P. Liu, H. Wu, Solid State Ionics 92, 91 (1996).

T.Pajkossy, L. Nyikos, Electrochim Acta 34, 171 (1989).

E. Barsoukov, J.R. Macdonald Impedance spectroscopy. Theory, experiment, and applications (Wiley-Interscience? NewJersey, 2005).

T. Uchida, Y. Morikawa, H. Ikuta, M. Wakihara, K. Suzuki, J. Electrochem. Soc. 143 (8), 2606 (1996).

N. Takami, A. Satoh, M. Hara, T. Ohsaki, J. Electrochem. Soc. 142 (2), 371 (1995).

A. Funabiki, M. Inaba, Z. Ogumi, J. Power Sources 68(2), 227 (1997).

N. Ding, J. Xu, Y.X. Yao, G. Wegner, X. Fang, C.H. Chen, I. Lieberwirth, Solid State Ionics 180 (2–3), 222 (2009).

R. Ruffo, S.S. Hong, C.K. Chan, R.A. Huggins, Y. Cui, J. Phys. Chem. C. 113(26), 11390 (2009).

J. Xie, N. Imanishi, T. Zhang, A. Hirano, Y. Takeda, O. Yamamoto, Mate. Chem. Phys. 120(2–3), 421 (2010).