Studies on structural, optical nonlinearity and antibacterial activity of Piperazine (bis) p-toluenesulfonate single crystal for optical limiting and biological applications

Array

Authors

  • K. Balakrishnan PG and Research Department of Physics, Nehru Memorial College (Autonomous), Affiliated to Bharathidasan University, Puthanampatti, India
  • S. Sakthy Priya PG and Research Department of Physics, Nehru Memorial College (Autonomous), Affiliated to Bharathidasan University, Puthanampatti, India; Department of Physics, Arignar Anna Government Arts College, Namakkal, Tamilnadu, India
  • A. Lakshmanan PG and Research Department of Physics, Nehru Memorial College (Autonomous), Affiliated to Bharathidasan University, Puthanampatti, India; Department of Physics, MAM College of Engineering, Siruganur, Tiruchirappalli, Tamilnadu, India
  • P. Surendran PG and Research Department of Physics, Nehru Memorial College (Autonomous), Affiliated to Bharathidasan University, Puthanampatti, India; Department of Physics, Government Arts and Science College, Komarapalayam, Tamilnadu, India
  • Karthik Kannan Chemical Sciences Department and the Radical Research Center, Ariel University, Ariel, Israel
  • P. Geetha Department of Physics, Quaid-E-Millath Government College for Women (Autonomous), Chennai, Tamilnadu, India
  • G. Vinitha Division of Physics, School of Advanced Sciences, VIT Chennai, Tamil Nadu, India
  • P. Praveen Kumar Department of Physics, Presidency College (Autonomous), Chepauk, Triplicane, Chennai, Tamilnadu, India
  • P. Rameshkumar Department of Physics, Presidency College (Autonomous), Chepauk, Triplicane, Chennai, Tamilnadu, India

DOI:

https://doi.org/10.15330/pcss.24.1.46-55

Keywords:

Crystal growth, optical material, Z-Scan, optical limiting, antibacterial activity

Abstract

Piperazine (bis) p-toluenesulfonate (PPTSA), an organic single crystal was synthesized and grown at environmental temperature by slow evaporation process using methanol as the solvent. The grown PPTSA crystal is from the triclinic system and belongs to the space group P1-. Powder X-ray diffraction was performed to ensure lattice parameters. Analysis and confirmation of functional groups and bonds were carried out through FT-IR spectral study. The optical characteristics were investigated using the UV-Vis spectrum such as the optical absorption, cut-off wavelength were calculated. The photoluminescence investigation was conducted to assess the luminous characteristics of grown crystal. The calculated NLO parameters like β, n2, and χ(3) were found to be 0.0495×10-4 (cm/W), 8.705×10-10 (cm2/W), 5.316×10-7 (esu) and Optical Limiting threshold value was found to be 3.074×10-3 (Wcm-2). Antibacterial studies were carried out to investigate the biological significance against selected foodborne germs.

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Published

2023-02-23

How to Cite

Balakrishnan, K., Sakthy Priya, S., Lakshmanan, A., Surendran, P., Kannan, K., Geetha, P., … Rameshkumar, P. (2023). Studies on structural, optical nonlinearity and antibacterial activity of Piperazine (bis) p-toluenesulfonate single crystal for optical limiting and biological applications: Array. Physics and Chemistry of Solid State, 24(1), 46–55. https://doi.org/10.15330/pcss.24.1.46-55

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Scientific articles (Physics)

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