The features of chemo-mechanical activation technology of polymer composite materials production


  • O.V. Komashko Vasyl Stefanyk Precarpathian National University, Ivano-Frankivsk, Ukraine
  • H.O. Sirenko Vasyl Stefanyk Precarpathian National University, Ivano-Frankivsk, Ukraine
  • M.B. Skladaniuk Vasyl Stefanyk Precarpathian National University, Ivano-Frankivsk, Ukraine



polymer composite, polytetrafluoroethylene, carbon fibers, chemo-mechanical activation technology


The paper deals with the study of the processes of obtaining polymer composites by chemo-mechanical activation technology (CMA-technology). The methods of research and testing of composite materials based on polytetrafluoroethylene (PTFE) and carbon fibers are analyzed and generalized. The influence of CMA technology on the structure and properties of PTFE composite was determined.


Handbook of engineering polymeric materials edited by Nicholas P. Cheremisinoff (Marcel Dekker inc., New York, 1997);

Sina Ebnesajjad, Fluoroplastics. Volume 2: Melt Processible Fluoropolymers - the Definitive User's Guide and Data Book (Elsevier Inc, 2016);

Sina Ebnesajjad, Introduction to Fluoropolymers. Materials, Technology, and Applications (Elsevier, 2021);

X. Huang, Fabrication and Properties of Carbon Fibers, Materials, 2(4), 2369 (2009);

К.O. Dyadyura, P. P. Savchuk, P.V. Rudenko, V. P. Kashyckiy, K.V. Berladir, Тhe method of obtaining a polymer composition based on polytetrafluoroethylene, Patent 110989 Ukraine, MPK C08J 5/00, C08L 27/00, opubl. 25.10.2016, Bul. № 20 (2016).

H.O. Sirenko, Antifriction carboplastics (Technika, Kiev, 1985).

E. Dhanumalayan, G.M. Joshi, Performance properties and applications of polytetrafluoroethylene (PTFE)—a review, Advanced Composites and Hybrid Materials,1, 247(2018);

H.O. Sirenko, L.M. Soltys, L.Y. Midak, I.V Kravets, Physico-chemistry of the surface of carbonized and graffitized fibers obtained by chemo-mechanical activation technology: 1. theoretical part and test methods, Herald of Vasyl Stefanyk Precarpathian National University. Series Chemistry, (XIV), 149 (2012).

A.F. Budnik, H.V. Berladіr, P.V. Rudenko, V.A. Svіders'kij, Patent 101976 U Ukraine, MPK C08J5/04, opubl. 12.10.2015, Bul. № 19 (2015).

L.V. Baziuk, H.O. Sirenko, A.F. Budnyk, S.P. Shapovalov, Seventh International Scientific and Practical Conference "Development of Scientific Research" (InterGraphics, Poltava, 2011) 48.

O.A Budnyk., K.V. Berladir, A.F. Budnyk, P.V. Rudenko, Structural changes in the matrix of PTFE-composites, Herald of Belarusian State Technical University named after V. H. Shukhov, (4), 104 (2015).

H.V. Berladir, T.P. Hovorun, S.G. Rudenko, O.A. Bilous, S.V. Varenyk, V.V. Kravets, D.V. Shvetsov, Mechanically activated polytetrafluoroethylene: morphology and supramolecular structure, Journal of Nano- and Electronic Physics, 14 (1), 01030 (2022);

Y. Sujuan, Z. Xingrong. Tribological properties of PTFE and PTFE composites at different temperatures, Tribology Transactions, 57(3), 382 (2014).

H.O. Sirenko, L.M. Soltys, M.B. Skladanyuk, Properties of carbon fibers (review), Herald of Vasyl Stefanyk Precarpathian National University. Series Chemistry, (ХIХ), 63 (2015);

A.F. Budnyk, Method of Producing Carbon Fiber Filler of PTFE-Matrix Composite, Patent 40960; Ukraine,MPK S08L27/00, 27 April 2009.

H.O. Sirenko, H.M. Sorokyn , A.F. Budnyk, O.M. Sirenko, Antifriction material: А.s. 1467893 (USSR), MKI B32B3/12; D04C5/00; F16C33/12/, №4261265, Published in 1989. - Bulletin № 11.

A.F. Budnyk, O. A. Budnyk, , Technological processes filler preparation and composition in production composite materials based on polytetrafluoroethylene, East-European Journal of Advanced Technologies, ¾ (27), 9 (2007).

Application of synthetic materials: conference materials, Editor-in-chief R.I. Silin. Kishinev: Cartea Moldoveiasca, P. 199 (1975).

H.O. Sirenko, L.M. Soltys, V.P. Svidersky, B.O. Talankin, Regularities of Change the Microroughness of Conjugated Surfaces the Polymer Composite – Metal in Mechano-physicalchemical Processes of Friction and Wear, Herald of Vasyl Stefanyk Precarpathian National University. Series Chemistry, (XV), 150 (2012).

V.P. Sviderskyi, L.M. Kyrychenko, A.I. Mishchyshyn, Increasing the wear resistance and mechanical characteristics of antifriction fluoroplastic carboplastics modified with zirconium oxide nanopowders, Increase of Machine and Equipment Reliability, 32 (2019);

A.F. Budnyk, H.V. Berladir,V.A. Svidersky, O.A. Budnyk, P.V. Rudenko, A.A. Ilyinik, Physicochemical aspects of mechanical activation of polytetrafluoroethylene composition during production and recycling, Eastern European Journal of Advanced Technologies, 2/11 (68), 9 (2014);

K.V. Berladir, T.P. Hovorun, V.A. Sviderskiy, P.V. Rudenko, M.E. Vyshehorodtseva, Nanostructural Modification of Polytetrafluoroethylene and its Composition by Energy Influence, Journal of Nano- and Electronic Physics, 8 (1), 01033(5) (2016);

O. A. Bilous, T. P. Hovorun, K. V. Berladir, S. I. Vorobiov, V. V. Simkulet, Mathematical modeling of the mechanical characteristic of the activated PTFE-matrix using the method of planning the experiment, Journal of Engineering Sciences, 5(1), C1 (2018),

K. Berladir, D. Zhyhylii, O. Gaponova, J. Krmela,V. Krmelová, A. Artyukhov, Modeling of Polymer Composite Materials Chaotically Reinforced with Spherical and Cylindrical Inclusions, Polymers, 14(10), 2087 (2022);

M. A. Markova, P. N. Petrova, Influence of Carbon Fibers and Composite Technologies on the Properties of PCM Based on Polytetrafluoroethylene, Inorganic Materials: Applied Research, 12, 551 (2021);

O. A. Bilous, T. P. Hovorun, K. V. Berladir., S. I. Vorobiov., V. V. Simkulet, Mathematical Modeling of the Mechanical Characteristic of the Activated PTFE-Matrix Using the Method of Planning the Experiment, Journal of Engineering Sciences, 5 (1), 1 (2018);

P.N. Grakovich, V.A . Shelestova, V.J . Shumskaja, et al. Influence of the Type of Carbon Fiber Filler on the Physical–Mechanical and Tribological Properties of PTFE Composites, J. Frict. Wear 40, 11 (2019);

L.V. Bazyuk, V.P. Svidersky, Influence of Type and Form of the Fillers on Therm ophysical Properties for composite M aterials on the base of the Polytetrafluoroetelene and Aromatic Polyam ide, Herald of Vasyl Stefanyk Precarpathian National University. Ser. Chemistry, (V), 47 (2008);

H.A.Sirenko, V.P.Sviderskiy, L.Ya.Midak, L.V.Karavanovich, Influence of temperature to a creep of composite materials because of polytetraftorethilene for want of by constant to a load, Polymer Journal 27 (3), 167 (2005).

H.O. Sirenko, V.P. Sviderskyi, L.V. Karavanovych. Influence of polymer composition on wear rate and thermal conductivity coefficient, Proc. of V International Scientific and Technical Conference "Wear resistance and reliability of friction units of machines (ZNM-2003), 27 (2003).

O.A.Budnik, A.F.Budnik, K.V.Berladir, P.V.Rudenko, V.A.Sviderskiy, Influence of mechanical activation of polytetrafluoroethylene matrix of tribotechnical composites on its structural and phase transformations and properties, Funct. Mater., 22 (4), 499 (2015);

A.F. Budnyk, V.A. Sviderskyi, A.O. Thomas, P.V. Rudenko, H.V. Berladir, Design of polymer composite modeled by spheres and ellipsoids by the criterion of coordination of properties, East-European Journal of Advanced Technologies, 2/5 (62), 20 (2013);

H.V. Berladir, V.A. Sviderskyi, Physical Modification fluoroplast-4 in order to improve tribotechnical properties of composites based on it, VI International scientific and technical conference of students, graduate students that young scientists "Chemistry and modern technologies", Dnepropetrovsk, 150 (2013).

H.O. Sirenko, L.M. Soltys, M.F. Semenyuk, The Specific Square of Gaussian Anisotropic and Isotropic Rough Surfaces, Herald of Vasyl Stefanyk Precarpathian National University. Ser. Chemistry, (XII), 134 (2011).




How to Cite

Komashko, O., Sirenko, H., & Skladaniuk, M. (2023). The features of chemo-mechanical activation technology of polymer composite materials production. Physics and Chemistry of Solid State, 24(2), 304–311.



Scientific articles (Chemistry)