Thermodynamic properties of the GdTe3 compound

Authors

  • Samira Imamaliyeva Institute of Catalysis and Inorganic Chemistry named after acad. M. Nagiyev

DOI:

https://doi.org/10.15330/pcss.22.3.420-425

Keywords:

gadolinium tellurides, EMF method, concentration cells, partial molar functions, thermodynamic functions

Abstract

The alloys of the Gd-Te system in the range of compositions > 75 at% Te were studied by the methods of
X-ray diffraction (XRD) and electromotive forces (EMF). From the EMF measurements of the concentration cells relative to the GdTe electrode in the 300-450 K temperature range, the partial thermodynamic functions of GdTe in alloys were determined. By combining these data with the corresponding functions of Gd in GdTe, the partial molar functions of gadolinium in GdTe3+Te alloys, and standard thermodynamic functions of formation and standard entropy of the GdTe3 compound were calculated. The obtained results were compared with the literature data.

References

A.R. Jha, Rare Earth Materials: Properties and Applications (CRC Press, United States, 2014).

A. Shankar, D.P. Rai, Sandeep, and R.K. Thapa, J. Semicond. 33(8), 082001 (2012); https://doi.org/10.1088/1674-4926/33/8/082001.

A. Kogar, Nature Physics 16(2), 1 (2020); http://dx.doi.org/10.1038/s41567-019-0705-3.

T. Vo, P. von Allmen, C-K. Huang, J. Ma, S. Bux, J-P. Fleurial, J. Appl. Phys. 116, 133701 (2014); https://doi.org/10.1063/1.4896670.

A. Sousanis, P.F. Smet, and D. Poelman, Materials (Basel). 10(8), 953 (2017); https://doi.org/10.3390/ma10080953.

I.P. Muthuselvam, R. Nehru, K.R. Babu, K. Saranya, S.N. Kaul, S-M. Chen, W-T. Chen, Y. Liu, G-Y. Guo, F. Xiu, R. Sankar, J. Physics: Condens. Matter. 31(28), 285802 (2019); https://doi.org/10.1088/1361-648X/ab1570.

J. Kim, K. Lee, T. Takabatake, H. Kim, M. Kim, M-H. Jung,. Sci Rep. 5, 10309 (2015); https://doi.org/10.1038/srep10309.

W. Boncher, H. Dalafu, N. Rosa, -S. Stoll. Coord Chem Rev. 289–290, 279 (2015); https://doi.org/10.1016/j.ccr.2014.12.008.

E Rogers, P Dorenbos, E van der Kolk, New J. Phys. 13, 093038 (2011); https://doi.org/10.1088/1367-2630/13/9/093038.

S-P. Guo, G-C. Guo, J. Mater. Chem. A, 2, 20621 (2014); https://doi.org/10.1039/C4TA04757E.

Y. Xing, Y. Li, Z. Yang, Z. Wang, P. Yang, J. Ge, Y. Liu, Y. Liu, T. Luo, Y. Tang, and J. Wang, J. Appl. Phys. 128, 073901 (2020); https://doi.org/10.1063/5.0012388.

K. Yumigeta, Y. Qin, H. Li, M. Blei, Y. Attarde, C. Kopas, S. Tongay, Adv. Sci. 2004762 (2021); https://doi.org/10.1002/advs.202004762.

O.V. Andreev, V.G. Bamburov, L.N.Monina, Razumkova, A.V. Ruseykina, O.Yu. Mitroshin, V.O. Andreev, Fazovie ravnovesiya v sistemax sulfidov 3d-, 4f-elementov. (RIO URO RAN, Ekatirinburg, 2015). (In Russian).

M.B. Babanly, E.V. Chulkov, Z.S. Aliev, A.V. Shevel’kov, and I.R. Amiraslanov, Russ. J. Inorg. Chem. 62(13), 1703 (2017); https://doi.org/10.1134/S0036023617130034.

S.Z. Imamaliyeva, Condensed Matter and Interphases 20(3), 332 (2018); https://doi.org/10.17308/kcmf.2018.20/570.

M.B. Babanly, L.F. Mashadiyeva, D.M. Babanly, S.Z. Imamaliyeva, D.B. Taghiyev, Y.A. Yusibov, Russ. J. Inorg. Chem. 64(13), 1649 (2019); https://doi.org/10.1134/S0036023619130035.

E.I. Yarembash, A.A. Eliseev, Chalcogenides of rare earth elements (Nauka. Moscow 1975).

T.B. Massalski, Binary alloys phase diagrams, second edition. (ASM International, Materials park, Ohio, 1990).

State diagrams of binary metallic systems: Handbook in 3 V. Ed. N.P. Lyakishev. (M.: Mashinostroenie. Moscow. 1996). (in Russian).

H. Poddig, T. Donath, P. Gebauer, K. Finzel, M. Kohout, Y. Wu, P. Schmidt, Th. Doert, Z. Anorg. Allg. Chem. 644, 1886 (2018); https://doi.org/10.1002/zaac.201800382.

O. Кubaschewski, C.B. Alcock. P. J. Spencer. Materials Thermochemistry (Oxford; New York: Pergamon Press, 1993).

Database of thermal constants of substances. Digital version, Eds.: V.S. Iorish and V.S. Yungman. (2006); http://www.chem.msu.ru/cgi-bin/tkv.pl (In Russian).

А.B.Aghayev, K.A.Sharifov, Ucheniye zapiski AGU. 72 (1972)

Vassiliev, V.A. Lysenko, Electrochim. Acta, 222, 1770 (2016); https://doi.org/10.1016/j.electacta.2016.11.075.

T.K. Azizov, A.B. Agaev, A.S. Abbassov, A.G. Gusenkov, Dokl. Akad. Nauk Az. SSR 36, 37 (1980).

K.C. Mills, Thermodynamic Data for Inorganic Sulphides, Selenides, and Tellurides (Butterworth, London, 1974).

V.P. Vassiliev, V. Lysenko, J. Bros, J. Alloys Compd. 790, 370 (2019); https://doi.org/10.1016/J.JALLCOM.2019.03.016.

E.G. Osadchii, Ya.I. Korepanov, N.N. Zhdanov, Instrum Exp Tech. 59(2), 302 (2016); https://doi.org/10.1134/S0020441216010255.

I.D. Alverdiev, S.M. Bagkheri, S.Z. Imamalieva, Y.A. Yusibov, M.B. Babanly, Russ. J. Electrochem. 53(5), 551 (2017); https://doi.org/10.1134/S1023193517050032.

M.V. Moroz, M.V. Prokhorenko, S.V. Prokhorenko, M.V. Yatskov. Russ.J. Phys.Chem.A. 92(1), 19 (2018); https://doi.org/10.1134/S0036024418010168.

S.Z.Imamaliyeva, D.M.Babanly, V.A.Qasymov, M.B.Babanly, JOM, 73, 1503 (2021). https://doi.org/10.1007/s11837-021-04623-z

S.Z. Imamaliyeva, I.F. Mehdiyeva, Y.I.Jafarov, M,B.Babanly, Bulletin of the University of Karaganda – Chemistry, 102(2), 43 (2021). https://doi.org/10.31489/2021Ch2/43-52

I.D. Alverdiev, S.Z. Imamalieva, D.M. Babanly, Y.A. Yusibov, D.B. Tagiev, M.B. Babanly, Russ. J. Electrochem. 55(5), 467 (2019); https://doi.org/10.1134/S1023193519050021.

S.Z. Imamaliyeva, D.M. Babanly, V.P. Zlomanov, D.B Taghiyev, M.B. Babanly, Condensed Matter and Interphases 4, 453 (2020); https://doi.org/10.17308/kcmf.2020.22/3116.

S.Z. Imamaliyeva, T.M. Gasanly, M.A. Mahmudova, F.M. Sadygov, Azerb. J. Physics. XXII(4), 19 (2017).

M.P. Pardo, O. Gorochov, J. Flahaut and L. Domange, Compt. Rend. 1666(9), 260 (1965).

C. Adenis, L. Langer, O. Lindqvist, Acta Crysallogr.Sec. C: Cryst. Struc. Commun. 45, 941 (1989).

M.B. Babanly, Yu.A. Yusibov, Electrochemical methods in thermodynamics of inorganic systems (ELM, Baku, 2011) (in Russian).

A.G. Morachevsky, G.F.Voronin, V.A. Geyderich, I.B. Kutsenok, Electrochemical research methods in the thermodynamics of metallic systems. Akademkniga Publ, (Moscow, 2003) (in Russian).

M.B. Babanly, Y.A. Yusibov, N.B. Babanly, In.: Electromotive force and measurement in several systems Ed.S.Kara. (Intechweb.Org, 2011); https://doi.org/10.5772/28934.

Downloads

Published

2021-07-17

How to Cite

Imamaliyeva, S. (2021). Thermodynamic properties of the GdTe3 compound. Physics and Chemistry of Solid State, 22(3), 420–425. https://doi.org/10.15330/pcss.22.3.420-425

Issue

Section

Scientific articles (Chemistry)